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In the following sequence of reactions, CH3CH2OHA B C D, then compound `D' is -      [AIEEE 2007]
  • a)
    Butanal 
  • b)
    N-butyl alcohol
  • c)
    N-propyl alcohol 
  • d)
    Propanal
Correct answer is option 'C'. Can you explain this answer?
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Verified Answer
In the following sequence of reactions, CH3CH2OHABCD, then compound `D...
Correct Answer is option C
When ethanol is treated with a mixture of phosphorus and iodine, ethyl iodide CH3​CH2​I is obtained. 
 
Compound A on reaction with Mg metal in ether forms ethyl magnesium iodide CH3​CH2​ MgI. 
 
The compound B reacts with formaldehyde to form compound C; CH3​CH2​−CH2​−OMgX which on hydrolysis gives n propyl alcohol CH3​CH2​CH2​−OH.
 
The compound D is n-propyl alcohol. 
 
Hence, option C is correct.
 
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In the following sequence of reactions, CH3CH2OHABCD, then compound `D...
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In the following sequence of reactions, CH3CH2OHABCD, then compound `D...
The compound A is Et-I B is Et-MgI C is Pr-OMgIAnd hence after hydrolysis compound D obtained is n propyl alcohol.
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Read the passage given below and answer the following questions:Reductive alkylation is the term applied to the process of introducing alkyl groups into ammonia or a primary or secondary amine by means of an aldehyde or ketone in the presence of a reducing agent. The present discussion is limited to those reductive alkylations in which the reducing agent is hydrogen and a catalyst or "nascent" hydrogen, usually from a metalacid combination; most of these reductive alkylations have been carried out with hydrogen and a catalyst. The principal variation excluded is that in which the reducing agent is formic acid or one of its derivatives; this modification is known as the Leuckart reaction. The process of reductive alkylation of ammonia consists in the addition of ammonia to a carbonyl compound and reduction of the addition compound or its dehydration product. The reaction usually is carried out in ethanol solution when the reduction is to be effected catalytically:Since the primary amine is formed in the presence of the aldehyde it may react in the same way as ammonia, yielding an additional compound, a Schiff's base (RCH= NCH2R) and finally, a secondary amine. Similarly, the primary amine may react with the imine, forming an addition product which also is reduced to a secondary amine Finally, the secondary amine may react with either the aldehyde or the imine to give products which are reduced to tertiary amines.Similar reactions may occur when the carbonyl compound employed is a ketone.Q. The reaction of ammonia and its derivatives with aldehydes is called

In the following sequence of reactions, CH3CH2OHABCD, then compound `D' is - [AIEEE 2007]a)Butanalb)N-butyl alcoholc)N-propyl alcohold)PropanalCorrect answer is option 'C'. Can you explain this answer?
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